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Cook quinoa according to package directions. Keep warm.
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Heat oven to 400 degrees. Heat oil in large ovenproof skillet over medium heat.
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Season pork chops with salt and pepper. Cook until browned, 5 minutes per side, and transfer to plate.
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Add peaches, onion and wine to skillet, tossing 1 minute.
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Return pork chops to skillet and transfer skillet to oven. Roast 30 minutes.
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Sprinkle with basil and serve with quinoa.